Synthesis and characterization of two novel Schiff base Pd(II) complexes based on 3,5-Diiodo- and 3,5-Dibromosalicylaldehydes

Authors

Alina A. Skorynina, The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, RussiaFollow
Aram L. Bugaev, The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, RussiaFollow
Vera V. Butova, The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, RussiaFollow
Olga A. Burachevskaia, The Smart Materials Research Institute, Southern Federal University, Sladkova 178/24, 344090 Rostov-on-Don, RussiaFollow
Pavel G. Morozov, Department of Chemistry, Southern Federal University, Zorge 7, 344090 Rostov-on-Don, RussiaFollow
Igor A. Estrin, Rostov State Transport University, Rostovskogo Strelkovogo Polka Narodnogo Opolcheniya Sq. 2, 344038 Rostov-on-Don, RussiaFollow

Abstract

We report on the synthesis and characterization of the two novel Schiff base Pd(II) complexes based on 3,5-diiodo- and 3,5-dibromosalicylaldehydes. Synthesis was made by the condensation method of these aldehydes with p-Anisidine. The structural features of the complexes were comprehensively analyzed by 1H nuclear magnetic resonance, X-ray diffraction, optical, vibrational and X-ray absorption spectroscopies. The analysis of experimental data supported by theoretical simulations at the density functional theory level confirmed the formation of the Pd(II) complexes, and provided detailed information on the local environment of the palladium atoms.

Recommended Citation

A. Skorynina, Alina; L. Bugaev, Aram; V. Butova, Vera; A. Burachevskaia, Olga; G. Morozov, Pavel; and A. Estrin, Igor (2024) "Synthesis and characterization of two novel Schiff base Pd(II) complexes based on 3,5-Diiodo- and 3,5-Dibromosalicylaldehydes," International Journal of Thin Film Science and Technology: Vol. 13 : Iss. 1 , PP -.
Available at: https://digitalcommons.aaru.edu.jo/ijtfst/vol13/iss1/1